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The first thing that will be important on a trip like this is that you make sure everyone on the trip has the proper equipment - including good hiking shoes and good sleeping equipment; without proper hiking shoes, the person in lack is likely to have a miserable time by the end of the journey, and without a good sleeping pad and sleeping bag, the night will be quite miserable, which will make the next day difficult to deal with in hiking back as well.
Having the right provisions will also be immensely important, in addition to having the right equipment; the first thing as far as "provisions" is that you make sure everyone brings enough water to last them for longer than needed, and secondly, make sure enough food is brought for everyone - lest everyone ends up having to go hungry!
And finally, you should be aware of the fact that things can happen when backpacking and/or camping - such as getting separated, getting lost, or getting hurt; make sure you have a plan in case these occurrences come about - realizing that you should always hope for the best, while also planning for the just-in-case worst.
When you keep these tips in mind in setting up your backpacking adventure, you will be able to ensure that everyone gets the most out of it - having a lot of fun during your "break from everyday life" - while also ensuring that no one gets stuck with too little food, too little water, or too few provisions to be properly comfortable!